Radical addition reactions of fluorinated species part 6. Regioselectivity of the addition of nucleophilic radicals to halogenopropenes and evidence for a steric effect of …
O Paleta, V Církva, Z Budková, S Böhm
Index: Paleta, Oldrich; Cirkva, Vladimir; Budkova, Zuzana; Boehm, Stanislav Journal of Fluorine Chemistry, 1997 , vol. 86, # 2 p. 155 - 171
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Citation Number: 15
Abstract
Nucleophilic radicals derived from alkanols and cyclic ethers (oxolane, 1, 3-dioxolane, 2, 2- dimethyl-1, 3-dioxolane) were employed to test the regioselectivity of addition to 3-chloro-1, 1, 2, 3, 3-pentafluoropropene (1), 1, 3-dichloro-1, 2, 3, 3-tetrafluoropropene (2), 1, 1, 3- trichloro2, 3, 3-trifluoropropene (3) and 1, 3-dichloro-2, 3, 3-trifluoropropene (4). The regioselectivity was strongly dependent on the number of chlorine atoms at the terminal ...
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