Ruthenium Hydride Catalyzed Regioselective Addition of Aldehydes to Enones To Give 1, 3??Diketones
T Fukuyama, S Minamino, S Omura…
Index: Fukuyama, Takahide; Doi, Takashi; Minamino, Satoshi; Omura, Sohei; Ryu, Ilhyong Angewandte Chemie - International Edition, 2007 , vol. 46, # 29 p. 5559 - 5561
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Citation Number: 51
Abstract
Despite the rapid progress in the development of metalcatalyzed cross-coupling reactions,[1] many challenges remain for the as yet unrealized classes of metal-catalyzed CÀC bondforming reactions. 1, 3-Diketones are important basic building blocks, which are traditionally prepared by the acylation of ketone enolates, or by an aldol reaction of enolates with aldehydes followed by oxidation.[2, 3] A transition-metal-based hydroacylation ...
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