Synthesis and Properties of 3-, 4-, and 5-Nitro-2-pyridinecarbaldehyde 2-pyridylhydrazones and Characterization of Their Metal Complexes.

T Odashima, K Sakakura, K Kohata, H Ishii

Index: Odashima, Tsugikatsu; Sakakura, Kei; Kohata, Katsunori; Ishii, Hajime Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 3 p. 797 - 803

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Abstract

Three hydrazones, 3-, 4-, and 5-nitro-2-pyridinecarbaldehyde 2-pyridylhydrazones, were synthesized. Their properties and reactivities with metal ions and the extraction and characteristics of the resultant complexes have been investigated and compared with one another. As a result, useful information on the molecular design of highly sensitive hydrazone reagents has been obtained.

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