Oxidation of alcohols, aldehydes, and carboxylates by the aquachromium (IV) ion
SL Scott, A Bakac, JH Espenson
Index: Scott, Susannah L.; Bakac, Andreja; Espenson, James H. Journal of the American Chemical Society, 1992 , vol. 114, # 11 p. 4205 - 4213
Full Text: HTML
Citation Number: 124
Abstract
Abstract: Four methods have been developed to prepare aquachromium (IV), which we believe to be an oxo ion, CrOZ+. It readily converts Ph3P to Ph3P0 (k= 2.1 X lo3 L mol-'SI) at 25 OC in 85% CH3CN/H20 (0.10 M HC104). The reactions used to form GO2+ are those between Cr2+ and (a) O2 (b) anaerobic Cr022+,(c) anaerobic CrOOCr4+, and (d) anaerobic TI (II1). The Cr02+ has a half-life of 30 s in acidic solution at room temperature and will ...
Related Articles:
Rhodium-Catalyzed Hydroformylation of Allyl Alcohol. A Potential Route to1, 4-Butanediol
[Pittman, Charles U.; Honnick, William D. Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2132 - 2139]
Rhodium-Catalyzed Hydroformylation of Allyl Alcohol. A Potential Route to1, 4-Butanediol
[Pittman, Charles U.; Honnick, William D. Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2132 - 2139]
A study of the catalytic deuteration of 1, 4-butynediol
[Chickos, James S.; Uang, Jack Y.-J.; Keiderling, Tim A. Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2594 - 2596]
Rhodium-Catalyzed Hydroformylation of Allyl Alcohol. A Potential Route to1, 4-Butanediol
[Pittman, Charles U.; Honnick, William D. Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2132 - 2139]
Synthesis and kinetic studies of a simple prostacyclin model
[Bergman, Nils-Ake; Jansson, Marie; Chiang, Yvonne; Kresge, A. Jerry; Yin, Ya Journal of Organic Chemistry, 1987 , vol. 52, # 20 p. 4449 - 4453]