… Pd-N Bond Rupture. X-ray Molecular Structure of [{Pd (η3-C4H7)} 2 (Me-BPzTO)](4-MeC6H4SO3)[Me-BPzTO= 4, 6-Bis (4-methylpyrazol-1-yl)-1, 3, 5-triazin-2-olate]
F Gomez-de la Torre, A de la Hoz, FA Jalon…
Index: Elguero, Jose; Fruchier, Alain; De La Hoz, Antonio; Jalon, Felix A.; Manzao, Blanca R.; Oteroo, Antonio; Torre, Felipe Gomez-De La Chemische Berichte, 1996 , vol. 129, # 5 p. 589 - 594
Full Text: HTML
Citation Number: 28
Abstract
Several bis-or tris (pyrazol-1-yl) triazine derivatives have been synthesized and used as ligands in the synthesis of cationic allyl-or bis (pentafluorophenyl) palladium complexes. In bis-palladated complexes hydrolysis of one pyrazole group is seen. The allyl palladium complexes show fluxional behavior, implying apparent π-allyl rotation and metallotropic shifts. Different activation energies, related to the strength of the Pd-N bond to be broken, ...
Related Articles:
Ligand-free Cu 2 O-catalyzed cross coupling of nitrogen heterocycles with iodopyridines
[Teo, Yong-Chua; Yong, Fui-Fong; Sim, Shirlyn Tetrahedron, 2013 , vol. 69, # 35 p. 7279 - 7284]
A manganese/copper bimetallic catalyst for C–N coupling reactions under mild conditions in water
[Teo, Yong-Chua; Yong, Fui-Fong; Lim, Gina Shiyun Tetrahedron Letters, 2011 , vol. 52, # 52 p. 7171 - 7174]
Efficient N-arylation catalyzed by a copper (I) pyrazolyl-nicotinic acid system
[Liu, Hai-Yang; Yu, Zhen-Tao; Yuan, Yong-Jun; Yu, Tao; Zou, Zhi-Gang Tetrahedron, 2010 , vol. 66, # 47 p. 9141 - 9144]
[Journal of Medicinal Chemistry, , vol. 47, # 19 p. 4645 - 4648]
[Journal of Organic Chemistry, , vol. 58, # 16 p. 4476 - 4478]