Hydration of olefins with molecular oxygen and triethylsilane catalyzed by bis (trifluoroacetylacetonato) cobalt (II).

S Isayama, T Mukaiyama

Index: Isayama, Shigeru; Mukaiyama, Teruaki Chemistry Letters, 1989 , p. 569 - 572

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Citation Number: 20

Abstract

572 Chanfiuylfiuem,1989 A typical procedure is described for the reaction of 1—benzoylamino—2— propene; a mixture of 1—benzoylamino-2—propene (161 mg, 1 mmol), triethylsilane (464 mg, 4 mmol) and bis(trifluoroacetylacetonato)cobalt(II) (19 mg, 0.05 mmol) in 1—propanol (5 ml) was stirred at 75 °C under an oxygen atmosphere for 24 h. After completion of the reaction, the volatile materials were evaporated under reduced ...