Isomerization of 1-decene by the nickel stearate-ethylaluminum chloride catalytic system

…, MA Demidov, VG Shamsutdinov, GL Il'yasov

Index: Startseva; Matkovskii; Churkina; Boiko; Knerel'man; Davydova; Troitskii; Aldoshin; Demidov; Shamsutdinov; Il'yasov Petroleum Chemistry, 2004 , vol. 44, # 1 p. 28 - 37

Full Text: HTML

Citation Number: 3

Abstract

The influence of the temperature, nature, and concentration of catalyst components on the conversion of 1-decene during its isomerization by the action of a Ni (OCOC17H35)(2)- (C2H5)(n) AlCl3-n (n= 1.0, 1.5) catalyst system was studied. It was shown that the 1-decene conversion increased from 19 to 100 wt% within 60 min as the nickel stearate concentration was increased from 0.00016 to 0.002 mol/l. The conditions of the process that ensure ...

Related Articles:

Detailed rate studies on the Wittig reaction of nonstabilized phosphorus ylides via phosphorus-31, proton, carbon-13 NMR spectroscopy. Insight into kinetic vs. …

[Maryanoff, Bruce E.; Reitz, Allen B.; Mutter, Martin S.; Inners, Ruth R.; Almond, Harold R. Jr. Journal of the American Chemical Society, 1985 , vol. 107, # 4 p. 1068 - 1070]

Application of indium ate complexes to synthetic chemistry. Selective conjugate addition to enones and coupling with allylic halides

[Araki, Shuki; Shimizu, Toshio; Jin, Shun-Ji; Butsugan, Yasuo Journal of the Chemical Society, Chemical Communications, 1991 , # 12 p. 824 - 825]

The effect of crown ether on steric hindrance to base approach in bimolecular elimination: evidence against clump aggregate model of ion-paired alkoxide base

[Pankova, Magdalena; Zavada, Jiri Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 11 p. 3150 - 3159]

Deoxygenation and desulfurization of organic compounds via transition metal atom cocondensation

[Togashi, Shigeo; Fulcher, John G.; Cho, Bong Rae; Hasegawa, Minoru; Gladysz, J.A. Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 3044 - 3053]

A Selective Ru??Catalyzed Semireduction of Alkynes to Z Olefins under Transfer??Hydrogenation Conditions

[Belger, Christian; Neisius, N. Matthias; Plietker, Bernd Chemistry - A European Journal, 2010 , vol. 16, # 40 p. 12214 - 12220]

More Articles...