Attempts at solvolytic generation of phenyl cations

K Laali, I Szele, K Yoshida

Index: Laali, Khosrow; Szele, Ivanka; Yoshida, Katsuhira Helvetica Chimica Acta, 1983 , vol. 66, # 6 p. 1710 - 1720

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Citation Number: 18

Abstract

Abstract New substrates and reaction conditions which may be expected to yield phenyl cation intermediates have been investigated. The approaches used were:(a) solvolysis of PhX in fluorinated alcohols, where X=[BOND] N (O)= NOTs (tosyloxyazoxy),[BOND] N (O)= NONf (Nf= C 4 F 9 SO math image) and [BOND] OSO 2 equation image (CH 3) 3 ŌTf (Tf= CF 3 SO math image);(b) solvolysis of ArBr, PhOTf and PhOSO 2 equation image (CH 3) 3 ...