Convergent stereocontrol in peterson olefinations. Application to the synthesis of (±)-3-hydroxybakuchiol and corylifolin
JB Perales, NF Makino…
Index: Michelot,D. et al. Bulletin de la Societe Chimique de France, 1976 , p. 1482 - 1488
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Citation Number: 23
Abstract
... The p-hydroxystyrene moiety of bakuchiol makes it unstable to both oxygen 6 and acid, 18 so it is not surprising that 3-hydroxybakuchiol 1 was ... 3-Hydroxybakuchiol decomposes in the presence of oxygen; a 1 H NMR sample stored in DMSO-d 6 at rt underwent nearly complete ...
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