Heteroatom Chemistry

Synthesis of [Zn (ΙΙ) BHPPDAH] as New Heterogeneous Catalyst without Being Immobilized on Any Support and Applied for Mannich Reaction

R Khalifeh, H Sharghi, Z Rashidi

Index: Khalifeh, Reza; Sharghi, Hashem; Rashidi, Zahra Heteroatom Chemistry, 2013 , vol. 24, # 5 p. 372 - 383

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Citation Number: 3

Abstract

ABSTRACT In this paper, a novel heterogeneous complex of zinc with N, N-bis (2- hydroxyphenyl) pyridine-2, 6-dicarboxamide (BHPPDAH) was synthesized. The catalyst was found to be a highly effective catalyst for the three-component coupling reactions of aldehydes, alkynes, and amines (A3 coupling) via C–H activation. The reactions could be applied to both aromatic and aliphatic aldehydes and alkynes. Nearly quantitative yields ...