Chemistry Letters

Alkenyldimethyl (2-thienyl) silanes, Excellent Coupling Partner for the Palladium-Catalyzed Cross-Coupling Reaction.

K Hosoi, K Nozaki, T Hiyama

Index: Hosoi, Kazushi; Nozaki, Kyoko; Hiyama, Tamejiro Chemistry Letters, 2002 , # 2 p. 138 - 139

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Citation Number: 42

Abstract

Introduction of a 2-thienyl group to the silicon atom of alkenylsilanes promoted the cross- coupling reaction with aryl halides mediated by tetrabutylammonium fluoride and a palladium catalyst. The reaction proceeded under extremely mild conditions to afford arylalkenes in high yields.

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