Chemische Berichte

Radikalumlagerungen, II. Wanderungsverhältnisse substituierter Phenylreste bei der Decarbonylierung von β??Aryl??isovaleraldehyden

C Rüchardt

Index: Ruechardt,C. Chemische Berichte, 1961 , vol. 94, p. 2609 - 2623

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Citation Number: 9

Abstract

Abstract Die in p-Stellung durch Cl-, CH 3 O-und CH 3-substituierten β-Phenyl- isovaleraldehyde III–V wurden dargestellt und bei verschiedenen Aldehyd- Anfangskonzentrationen der peroxydkatalysierten Decarbonylierung unterworfen. Die gefundenen relativen Wanderungsverhältnisse, p-Chlorphenyl 1.82, unsubst,[TRIPLE BOND] 1.0, p-Tolyl 0.65, p-Methoxy-phenyl 0.35 folgen angenähert einer Hammett- ...

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