Solvent hydrogen bonding and structural influences on the CrVI oxidation of anilines in aqueous acetic acid medium
DS Bhuvaneshwari, KP Elango
Index: Bhuvaneshwari; Elango Journal of the Indian Chemical Society, 2009 , vol. 86, # 3 p. 242 - 249
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Citation Number: 9
Abstract
Résumé/Abstract The oxidation of meta-and para-substituted anilines by Cr VI oxidant, imidazolium fluorochromate (IFC), in aqueous acetic acid mixtures of varying compositions in the presence of p-toluenesulfonic acid (PTS) is first order in IFC and PTS. Michaelis- Menten type kinetics is observed with all of the anilines. The IFC oxidation of 15 meta-and para-substituted anilines at 299-322 K complies with the isokinetic relationship but not to ...
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