Gemischte organozinkverbindungen durch austauschreaktionen von diorganozinkverbindungen

H Nehl, WR Scheidt

Index: Nehl, Hans; Scheidt, Walter R. Journal of Organometallic Chemistry, 1985 , vol. 289, p. 1 - 8

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Citation Number: 22

Abstract

Abstract The exchange of organyl groups between various diorganozinc compounds, R 2 1 Zn (R 1= CHMe 2 (1), CH 2 (CH 2) 2 Me (2), CH 2 C (Me) CH 2 (3), CH 2 CH CHMe (4)) and R 2 2 Zn (R 2= Et (5), CH (Me) Et (6), CH 2 (CH 2) 3 Me (7), CMe 3 (8), Menthyl (9), Ph (10), Cyclohexyl (11)), has been followed by mass spectroscopy: molecular ions for the mixed compounds R 1 R 2 Zn were observed. The exchange equilibrium constants for 1– ...