Reaction of lithium aluminum hydride with hindered phenols. Formation of tricoordinate aluminum species
H Haubenstock, TA Mester Jr…
Index: Haubenstock, Howard; Mester, Theodore A.; Zieger, Herman Journal of Organic Chemistry, 1980 , vol. 45, # 17 p. 3443 - 3448
Full Text: HTML
Citation Number: 8
Abstract
Lithium aluminum hydride reacts readily with 3 molar equiv of 2, 4, 6-tri-tert-butylphenol in refluxing ether. It has been demonstrated that the products resulting from this reaction cause the conversion of axial to equatorial cyclohexanols in the presence of a ketone. This behavior is attributed to the formation of tricoordinate aluminum species. An ether solution of bis (2, 4, 6-tri-tert-butylphenoxy) aluminum hydride was prepared, and infrared spectra ...
Related Articles:
[Ashby, Eugene C.; Noding, Stephen A.; Goel, Anil B. Journal of Organic Chemistry, 1980 , vol. 45, # 6 p. 1028 - 1035]
Directing effects in homogeneous hydrogenation with [Ir (cod)(PCy3)(py)] PF6
[Crabtree, Robert H.; Davis, Mark W. Journal of Organic Chemistry, 1986 , vol. 51, # 14 p. 2655 - 2661]
[Feghouli, G.; Vanderesse, R.; Fort, Y.; Caubere, P. Tetrahedron Letters, 1988 , vol. 29, # 12 p. 1383 - 1384]
Reduction of isophorone with sodium borohydride: change in regioselectivity with hydrotropes
[Laxman, Mahalaxmi; Sharma, Man Mohan Synthetic Communications, 1990 , vol. 20, # 1 p. 111 - 117]
[Schneider, Hans-Joerg; Becker, Norman; Schmidt, Guenther; Thomas, Fred Journal of Organic Chemistry, 1986 , vol. 51, # 19 p. 3602 - 3607]