Tetrahedron letters

Iodofluorination of alkenes and alkynes promoted by iodine and 4-iodotoluene difluoride

P Conte, B Panunzi, M Tingoli

Index: Conte, Pellegrino; Panunzi, Barbara; Tingoli, Marco Tetrahedron Letters, 2006 , vol. 47, # 3 p. 273 - 276

Full Text: HTML

Citation Number: 21

Abstract

It was found that a mixture of molecular iodine and 4-iodotoluene difluoride are useful to generate in situ the couple 'IF' that was able to add in a Markovnikov fashion and with prevalent anti-stereoselectivity to various alkenes and alkynes. ... A mixture of molecular iodine and 4-iodotoluene difluoride generated in situ the couple 'IF' able to add in a Markovnikov fashion to various alkenes and alkynes. ... In a preliminary experiment, cheaper sodium iodide was selected as a ...

Related Articles:

Tandem Synthesis of 3-Chloro-4-iodoisoxazoles from 1-Copper (I) Alkynes, Dichloroformaldoxime, and Molecular Iodine

[Wang, Bo; Zhang, Jianlan; Wang, Xinyan; Liu, Nan; Chen, Wenwen; Hu, Yuefei Journal of Organic Chemistry, 2013 , vol. 78, # 20 p. 10519 - 10523]

Methyl group migration in the reactions of alkynyltrialkylborates

[Pelter, Andrew; Drake, Robert A. Tetrahedron Letters, 1988 , vol. 29, # 33 p. 4181 - 4184]

Copper-Mediated Nucleophilic Displacement Reactions of 1-Haloalkynes. Halogen-Halogen Exchange and Sulfonylation.

[Abe, Hajime; Suzuki, Hitomi Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 4 p. 787 - 798]

Terminal 1-halo-1 and 1-pseudohalo-1-alkynes via bis (trimethylsilyl) peroxide (BTMSPO) promoted Umpolung transfer of Halides and pseudohalides.

[Casarini; Dembech; Reginato; Ricci; Seconi Tetrahedron Letters, 1991 , vol. 32, # 19 p. 2169 - 2170]

Synthesis of trimethylsilyloxy and hydroxy compounds from carbanions and bis (trimethylsilyl) peroxide

[Camici, Lucia; Dembech, Pasquale; Ricci, Alfredo; Seconi, Giancarlo; Taddei, Maurizio Tetrahedron, 1988 , vol. 44, # 13 p. 4197 - 4206]

More Articles...