Novel Iron (II) Microporous Spin-Crossover Coordination Polymers with Enhanced Pore Size

FJ Muñoz-Lara, AB Gaspar, MC Muñoz…

Index: Munoz-Lara, Francisco J.; Gaspar, Ana B.; Munoz, M. Carmen; Ksenofontov, Vadim; Real, Jose Antonio Inorganic Chemistry, 2013 , vol. 52, # 1 p. 3 - 5

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Citation Number: 8

Abstract

In this Communication, we report the synthesis and characterization of novel Hofmann-like spin-crossover porous coordination polymers of composition {Fe (L)[M (CN) 4]}· G [L= 1, 4- bis (4-pyridylethynyl) benzene and M= Ni, Pd, and Pt]. The spin-crossover properties of the framework are tightly related with the number and chemical nature of the guest molecules included in the pores.