Pd-Catalyzed P–C Cross-Coupling Reactions for Versatile Triarylphosphine Synthesis

…, T Matsuura, I Tanaka, H Ohta, Y Watanabe

Index: Hayashi, Minoru; Matsuura, Takashi; Tanaka, Ippei; Ohta, Hidetoshi; Watanabe, Yutaka Organic Letters, 2013 , vol. 15, # 3 p. 628 - 631

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Citation Number: 13

Abstract

Practical and versatile syntheses of tertiary phosphine derivatives have been achieved by palladium-catalyzed deformylative P–C cross-coupling reactions of hydroxymethylphosphine derivatives. Sequential couplings of orthogonally protected precursors provide a simple and practical route toward a variety of tertiary phosphine derivatives having aryl substituents in any combination.