Synthesis of dimethyl adipate from cyclopentanone and dimethyl carbonate over solid base catalysts
DD Wu, Z Chen, ZB Jia, L Shuai
Index: Wu, Dudu; Chen, Zhi; Jia, Zhenbin; Shuai, Li Science China Chemistry, 2012 , vol. 55, # 3 p. 380 - 385
Full Text: HTML
Citation Number: 0
Abstract
Abstract A facile route for the synthesis of dimethyl adipate (DAP) from cyclopentanone and dimethyl carbonate (DMC) in the presence of solid base catalysts has been developed. It was found that the intermediate carbomethoxycyclopentanone (CMCP) was produced from cyclopentanone with DMC in the first step, and then CMCP was further converted to DAP by reacting with a methoxide group. The role of the basic catalysts can be mainly ascribed to ...
Related Articles:
Condensation of ketones in the presence of titanium alkoxides
[Yatluk; Sosnovskikh; Suvorov Russian Journal of Organic Chemistry, 2004 , vol. 40, # 6 p. 763 - 765]
[Fotie, Jean; Ayer, Suraj K.; Poudel, Binit S.; Reid, Carolyn S. Tetrahedron Letters, 2013 , vol. 54, # 51 p. 7069 - 7073]
[Rodrigues, Shirley M. M.; Nardini, Viviani; Constantino, Mauricio G.; Da Silva, Gil Valdo J. Tetrahedron Letters, 2012 , vol. 53, # 45 p. 6136 - 6137,2]
A selective solvent-free self-condensation of carbonyl compounds utilizing microwave irradiation
[Sharma, Lalit Kumar; Kim, Kyung Bo; Elliott, Gregory I. Green Chemistry, 2011 , vol. 13, # 6 p. 1546 - 1549]
Trisannelated benzene synthesis by copper (II) chloride
[Mahmoodi, Nosrat O.; Hajati, Nezam Journal of the Chinese Chemical Society, 2002 , vol. 49, # 1 p. 91 - 94]