Total synthesis of korormicin

Y Kobayashi, S Yoshida…

Index: Kobayashi, Yuichi; Yoshida, Shinya; Nakayama, Yuji European Journal of Organic Chemistry, 2001 , # 10 p. 1873 - 1881

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Citation Number: 9

Abstract

Abstract Recently, we have assigned the (5S, 3′ R, 9′ S, 10′ R) stereochemistry to planar korormicin (1) on the basis of the specific rotations of the four possible diastereoisomers [ie,(5S, 3′ R, 9′ S, 10′ R),(5S, 3′ S, 9′ S, 10′ R),(5S, 3′ S, 9′ R, 10′ S), and (5S, 3′ R, 9′ R, 10′ S) isomers], which were prepared by a total synthesis. In this article, we describe the synthetic aspects in detail. The intermediates in the ...