Synthesis of methylenecyclopropene

WE Billups, LJ Lin, EW Casserly

Index: Billups,W.E.; Lin,L.J.; Casserly,E.W. Journal of the American Chemical Society, 1984 , vol. 106, p. 3698

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Citation Number: 77

Abstract

I considerable research effort.'Physical evidence for the parent hydrocarbon is, however, completely lacking despite the intense theoretical interest in this molecule. 2 We now wish to report the synthesis and characterization of this compound. The starting material z3 was prepared from allene and chlorocarbene (CH2C12, CH3Li). 4 The bromide 3 is an equally

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