THE REDUCING ACTION OF THE GRIGNARD REAGENT AND THE SYNTHESIS OF TERTIARY ALIPHATIC CARBINOLS

AH Blatt, JF Stone Jr

Index: Blatt; Stone Journal of the American Chemical Society, 1932 , vol. 54, p. 1496,1498

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Citation Number: 2

Abstract

2. These reactions are based on the fact that while 2, 3-dimethylglucose gives a di-nitrate, only the nitrate group in position 6 is replaceable by iodine. It was therefore possible to restrict the introduction of the third methyl group to position 6 as positions 4 and 5 were masked.