Neodymium tris-diarylphosphates: Systematic study of the structure–reactivity relationship in butadiene and isoprene polymerisation

IE Nifant'ev, AN Tavtorkin, AK Sof'ya…

Index: Nifant'Ev, Ilya E.; Tavtorkin, Alexander N.; Korchagina, Sof'Ya A.; Gavrilenko, Inna F.; Glebova, Nataliya N.; Kostitsyna, Nataliya N.; Yakovlev, Vladimir A.; Bondarenko, Galina N.; Filatova, Marina P. Applied Catalysis A: General, 2014 , vol. 478, p. 219 - 277

Full Text: HTML

Citation Number: 3

Abstract

Abstract The catalytic properties of neodymium tris-phosphates with various diarylphosphate ligands in the stereoregular 1, 4-cis-polymerisation of butadiene and isoprene were studied. The considerable variability of the diaryl phosphate structure allowed for the systematic investigation of the dependence of the catalytic properties of neodymium tris- diarylphosphates on the electronic and steric properties of the ligand. Electron- ...