Regioselective synthesis of 1-formylcyclohexenes by one-carbon homologation
JW Huffman, MJ Wu, HH Joyner
Index: Huffmann, John W.; Wu, Ming-Jung; Joyner, H. Howard Journal of Organic Chemistry, 1991 , vol. 56, # 17 p. 5224 - 5226
Full Text: HTML
Citation Number: 3
Abstract
1 R-MeorMOM cursor to 11-nor-9-carboxy-Ag-tetrahydrocannabinol 3, a human metabolite of Ag-tetrahydrocannabinol, the major active component of marijuana. Although a number of procedures have been described for the preparation of unsaturated aldehydes by one- carbon homologation, 2 only two appeared attractive for the synthesis of 2. One of these, developed by Denmark,% proceeds by conjugate reduction of an enone, trapping the ...
Related Articles:
Palladium-catalyzed formylation of organic halides with carbon monoxide and tin hydride
[Baillargeon,V.P.; Stille,J.K. Journal of the American Chemical Society, 1986 , vol. 108, p. 452]
Palladium Catalysts for the Formylation of Vinyl Triflates To Form α, β??Unsaturated Aldehydes
[Neumann, Helfried; Sergeev, Alexey; Beller, Matthias Angewandte Chemie - International Edition, 2008 , vol. 47, # 26 p. 4887 - 4891]
[Tamura, Rui; Sato, Masahiro; Oda, Daihei Journal of Organic Chemistry, 1986 , vol. 51, # 23 p. 4368 - 4375]
[Tamura, Rui; Sato, Masahiro; Oda, Daihei Journal of Organic Chemistry, 1986 , vol. 51, # 23 p. 4368 - 4375]
Bacteriorhodopsin: The influence of the cyclohexene??ring methyls
[Courtin, J. M. L.; Verhagen, L.; Biesheuvel, P. L.; Lugtenburg, J.; Bend, R. L. van der; Dam, K. van Recueil des Travaux Chimiques des Pays-Bas, 1987 , vol. 106, # 4 p. 112 - 119]