Palladium-catalyzed formylation of organic halides with carbon monoxide and tin hydride

VP Baillargeon, JK Stille

Index: Baillargeon,V.P.; Stille,J.K. Journal of the American Chemical Society, 1986 , vol. 108, p. 452

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Citation Number: 183

Abstract

Palladium-Catalyzed Formylation of Organic Halides with ... Contribution from the Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523. Received July 8, 1985 ... Abstract: The palladium-catalyzed formylation of a wide variety of organic substrates (aryl iodides, benzyl halides, vinyl iodides, vinyl triflates, and allylic halides) with tin hydride and carbon monoxide gives good yields of aldehydes under mild conditions (50 OC, 1-3 atm of CO, ...

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