1-Oxa-2-Silacycloalkanes and their Conversion to Bis-(hydroxyalkyl)-disiloxanes
WH Knoth Jr, RV Lindsey Jr
Index: Knoth; Lindsey Journal of the American Chemical Society, 1958 , vol. 80, p. 4106
Full Text: HTML
Citation Number: 37
Abstract
The (ch1oroalkoxy)-chlorosilanes were obtained by two routes. Those in which n= 3 were obtained from the appropriate disubstituted dichlorosilane and trimethylene chlorohydrin with triethylamine as acid acceptor. Compounds in which n= 4 and 5 were prepared smoothly and in good yields by heating the dichlorosilanes with tetrahydrofuran and tetrahydropyran, respectively, to 200'in an autoclave.'At 250, tetrahydro-
Related Articles:
Intramolecular radical hydrosilylation—the first radical 5-endo-dig cyclisation
[Amrein, Stephan; Studer, Armido Chemical Communications, 2002 , # 15 p. 1592 - 1593]
[Nakadaira, Yasuhiro; Sekiguchi, Akira; Funada, Yasuhito; Sakurai, Hideki Chemistry Letters, 1991 , # 2 p. 327 - 330]
Quinone chemistry. Synthesis of a masked naphthazarin synthon
[Tzeng, Dongjaw; Weber, William P. Journal of Organic Chemistry, 1982 , vol. 47, # 10 p. 1976 - 1977]
Mechanism of the reactions of dimethylsilylene with oxetanes
[Gu, Tai-Yin Yang; Weber, William P. Journal of the American Chemical Society, 1980 , vol. 102, # 5 p. 1641 - 1644]
Silicon Tethered Alkenyl Transfer and Type I Ene Reactions
[Robertson, Jeremy; O'Connor, Garry; Ringrose, Caroline L.; Middleton, Donald S. Tetrahedron, 2000 , vol. 56, # 42 p. 8321 - 8333]