Chemistry–A European Journal

Iridium??Catalyzed Enantioselective Hydrogenation of Alkenylboronic Esters

A Ganić, A Pfaltz

Index: Ganic, Adnan; Pfaltz, Andreas Chemistry - A European Journal, 2012 , vol. 18, # 22 p. 6724 - 6728

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Citation Number: 20

Abstract

Chiral boronates represent highly versatile building blocks in organic synthesis,[1] since carbon–boron bonds can be readily converted into CÀO, CÀN, and CÀC bonds in a stereospecific manner.[2] Therefore, enantioselective routes to these compounds are of great value. The most widely used method for the synthesis of enantioenriched chiral boronic esters is the hydroboration of C= C bonds with chiral hydroboranes pioneered by ...

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