New oxidative demetalation protocol for molybdenum π-complexes: Enantiocontrolled synthesis of unsaturated ketones and lactones

A Alcudia, RG Arrayás…

Index: Julia,M.; Blasioli,C. Bulletin de la Societe Chimique de France, 1976 , p. 1941 - 1946

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Abstract

... In 1976 Faller reported that CpMo(CO) 2 (η 3 -allyl) (Cp = η 5 -cyclopentadienyl) complexes are easily converted to allyl cation equivalents by replacement of one CO ligand with NO + using NOBF 4 . 2,3 Treatment of the resulting [CpMo(CO)(NO ... HRMS [M + ]: calcd for C 11 H ...

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