Reactions of (Et2NCH2CH2NEt2)· H2SiCl2 with Selected Diorganometallic Reagents of Magnesium and Lithium†

JY Corey, KA Trankler, J Braddock-Wilking…

Index: Corey, Joyce Y.; Trankler, Kevin A.; Braddock-Wilking, Janet; Rath, Nigam P. Organometallics, 2010 , vol. 29, # 21 p. 5708 - 5713

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Citation Number: 7

Abstract

Reaction of the six-coordinate complex [(teeda)· H2SiCl2](teeda= tetraethylethylenediamine ) with two types of diorganometallic reagents produced either a dibenzheterocycle (silafluorene and phenazasiline) or the corresponding spirocycle as the major product, depending on reaction conditions.

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