Scandium (III) catalysis of transimination reactions. Independent and constitutionally coupled reversible processes
N Giuseppone, JL Schmitt, E Schwartz…
Index: Giuseppone, Nicolas; Schmitt, Jean-Louis; Schwartz, Evan; Lehn, Jean-Marie Journal of the American Chemical Society, 2005 , vol. 127, # 15 p. 5528 - 5539
Full Text: HTML
Citation Number: 71
Abstract
Sc (OTf) 3 efficiently catalyzes the self-sufficient transimination reaction between various types of CN bonds in organic solvents, with turnover frequencies up to 3600 h-1 and rate accelerations up to 6× 105. The mechanism of the crossover reaction in mixtures of amines and imines is studied, comparing parallel individual reactions with coupled equilibria. The intrinsic kinetic parameters for isolated reactions cannot simply be added up when several ...
Related Articles:
Axial/equatorial populations in α??hetero??substituted cyclohexanone Oximes and O??methyl oximes
[Ribeiro, Douglas S.; Olivato, Paulo R.; Rittner, Roberto Magnetic Resonance in Chemistry, 2000 , vol. 38, # 8 p. 627 - 638]
[Shono, Tatsuya; Kise, Naoki; Fujimoto, Taku; Yamanami, Ayuko; Nomura, Ryoji Journal of Organic Chemistry, 1994 , vol. 59, # 7 p. 1730 - 1740]
O-Methylation of Aromatic (E)-Oximes by Dimethylsulfonium Methylide
[Tanimoto,S. et al. Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 627 - 628]