Diastereoselective synthesis of functionalized 9-ring ethers (oxonins)
A Brandes, HMR Hoffmann
Index: Brandes, Arndt; Hoffmann, H. M. R. Tetrahedron, 1995 , vol. 51, # 1 p. 145 - 154
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Citation Number: 18
Abstract
In response to the challenge of preparing medium ring ethers of the Laurencia class, a simple synthesis of functionalized, acyclic α, α′-chiral disecondary ethers has been developed. Stereocontrolled cyclization to 9-membered rings was effected in overall high yield by Pd (0) catalyzed allylic alkylation.
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