A novel transformation of a carbonyl to a CF2 group
S Rozen, M Brand, D Zamir
Index: Rozen, Shlomo; Brand, Michael; Zamir, Dov; Hebel, David Journal of the American Chemical Society, 1987 , vol. 109, # 3 p. 896 - 897
Full Text: HTML
Citation Number: 31
Abstract
The construction of the CF2 moiety is of importance to organic chemistry from several aspects, including some of considerable biological interest.'This has led to the development of a few general, but somewhat limited, methods for its construction. Thus the incorporation of the CF2 unit into a target molecule can be accomplished by using ethylbromodifluoro acetate2 or CF, containing F re~ ns.~ Another method, limited to the construction of a ...
Related Articles:
Conversion of the carbonyl group to CF2 using iodine monofluoride (IF)
[Journal of Organic Chemistry, , vol. 56, # 15 p. 4695 - 4700]
[Das, Saibal; Chandrasekhar, Srivari; Yadav, Jhillu Singh; Gree, Rene Tetrahedron Letters, 2007 , vol. 48, # 30 p. 5305 - 5307]
A novel transformation of a carbonyl to a CF2 group
[Journal of the American Chemical Society, , vol. 109, # 3 p. 896 - 897]
Direct fluorination of aryl ketone hydrazones
[Patrick,T.B.; Flory,P.A. Journal of Fluorine Chemistry, 1984 , vol. 25, p. 157]
Vicinal bromofluoroalkanes: their regioselective formation and their conversion to fluoroolefins
[Suga, Hiroaki; Hamatani, Takeshi; Guggisberg, Yves; Schlosser, Manfred Tetrahedron, 1990 , vol. 46, # 12 p. 4255 - 4260]