Organic letters

Deprotonative C–H Silylation of Functionalized Arenes and Heteroarenes Using Trifluoromethyltrialkylsilane with Fluoride

M Sasaki, Y Kondo

Index: Taneda, Hiroshi; Inamoto, Kiyofumi; Kondo, Yoshinori Chemical Communications, 2014 , vol. 50, # 49 p. 6523 - 6525

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Citation Number: 4

Abstract

A highly selective C–H silylation reaction of functionalized arenes and heteroarenes was developed using Ruppert–Prakash reagent (TMSCF3) activated by alkali metal fluoride. TMSCF3 is considered to play dual roles as a precursor of a mild base and also as a silicon

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