Photochemical reaction between 1, 4-naphthalenedicarbonitrile and. alpha.-substituted benzylic derivatives
A Sulpizio, A Albini, N d'Alessandro…
Index: Sulpizio, Ada; Albini, Angelo; d'Alessandro, Nicola; Fasani, Elisa; Pietra, Silvio Journal of the American Chemical Society, 1989 , vol. 111, # 15 p. 5773 - 5777
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Citation Number: 42
Abstract
Abstract: The photochemical reaction of 1, 4-naphthaIenedicarbonitrile (NDN) with benzylic derivatives of the general formula PhCHRX (R= H, Ph; X= H, C, 0, S, Si, Sn-bonded substituents) has been investigated. The competition between CH and CX bond cleavage in the photochemically created radical cation PhCHRX" is revealed by the different chemical products formed, viz. 5, 1l-methanodibenzo [a, e] cyclooctenes (2), from proton transfer ...
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