Electrolytic partial fluorination of organic compounds. Part 78: Regioselective anodic fluorination of 2-oxazolidinones
Y Cao, K Suzuki, T Tajima, T Fuchigami
Index: Cao, Yi; Suzuki, Katsutoshi; Tajima, Toshiki; Fuchigami, Toshio Tetrahedron, 2005 , vol. 61, # 28 p. 6854 - 6859
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Citation Number: 6
Abstract
Various 2-oxazolidinones were galvanostatically electrooxidized in the presence of various fluoride salts. It was found that a fluorine atom was introduced to the α-position of the nitrogen atom of N-acyl-and N-alkoxycarbonyl-2-oxazolidinones to provide the corresponding α-fluorinated products in moderate to good yields. In the case of N- phenoxycarbonyl derivative, fluorination took place on the phenyl group selectively.
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