Cyclic isomers and cyclodimers of 3-oxo-1-silaprop-1-enes
G Mass, K Schneider, W Ando
Index: Maas, Gerhard; Schneider, Klaus; Ando, Wataru Journal of the Chemical Society, Chemical Communications, 1988 , # 1 p. 72 - 74
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Abstract
3-Oxo-1-silaprop-1-enes, when generated by photochemical decomposition of α-diazo-α- silyl carbonyl compounds, cyclize to 1-oxa-2-silacyclobut-3-enes provided that the substituent at C-3 is sterically demanding; otherwise, the head-to-tail cyclodimers (1, 5-dioxa- 2, 6-disilacyclo-octa-3, 7-dienes) are obtained.
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