Tetrahedron letters

Hochsubstituierte tricyclopentanone und cyclopropenyldiazomethane-vorstufen für tetrahedrane?

G Maier, KA Reuter, L Franz, HP Reisenauer

Index: Maier, Guenter; Reuter, Karl Arnold; Reisenauer, Hans Peter Tetrahedron Letters, 1985 , vol. 26, # 15 p. 1845 - 1848

Full Text: HTML

Citation Number: 11

Abstract

Abstract Reaction of tri-tert-butylcyclopropenylium tetrafluoroborate (= 7) with the Li-salt of tert-butyldiazomethane leads to the astonishingly stable diazo compound (= 6). The trimethylsilyl derivative (= 8) can be prepared via the same route. On photolysis or pyrolysis both cyclopropenyldiazomethanes are fragmented into the corresponding acetylenes.

Study of an Unexpected Rearrangement of the α-Phenyl Pyrane Derivatives Prepared via Hetero-Diels− Alder Reaction of Acyclic Vinyl Allenes and Aldehydes

[Yeager, Adam R.; Min, Geanna K.; Porco Jr., John A.; Schaus, Scott E. Organic Letters, 2006 , vol. 8, # 22 p. 5065 - 5068]

Interactions of Tetrahedrane and Tetrasilatetrahedrane with CH2 and SiH2: A Computational Study†

[Maier, Guenther; Born, Dieter; Bauer, Ines; Wolf, Reinhard; Boese, Roland; Cremer, Dieter Chemische Berichte, 1994 , vol. 127, # 1 p. 173 - 190]

Unique σ-Bond Metathesis of Silylalkynes Promoted by an a nsa-Dimethylsilyl and Oxo-Bridged Uranium Metallocene

[Wang, Jiaxi; Gurevich, Ylia; Botoshansky, Mark; Eisen, Moris S. Journal of the American Chemical Society, 2006 , vol. 128, # 29 p. 9350 - 9351]