Direct Formation and Reaction of Functionalized thienyl-Based Organocopper Reagents

…, TC Wu, DE Stinn, RM Wehmeyer

Index: Rieke, Reuben D.; Wu, Tse-Chong; Stinn, Dean E.; Wehmeyer, Richard M. Synthetic Communications, 1989 , vol. 19, # 11-12 p. 1833 - 1840

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Citation Number: 27

Abstract

Abstract: Highly reactive copper solutions have been prepared by the direct reduction of lithium 2-thienylcyanocuprate. Product isolation was much easier using the thienyl-based organocopper reagents as opposed to phosphine-based organocopper reagents. ... We have previously reported that highly reactive copper ... In our search for a more reactive copper solution that did not ... 2-thienylcyanocuprate to form higher-order mixed organocuprates

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