A FURTHER STUDY OF THE INTERACTION OF SULFUR AND PARA-TOLUIDINE IN THE PRESENCE OF LITHARGE: THIO-PARA-TOLUIDINE AND RELATED …

MT Bogert, L Smidth

Index: Bogert; Smidth Journal of the American Chemical Society, 1928 , vol. 50, p. 434

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Abstract

The yield of tert.-butylmagnesium bromide in one of the smaller-sized runs was 33.1%. Under corresponding conditions the yield of tert.- butylmagnesium chloride was 49.71%. Earlier results by Gilman and McCracken under different conditions showed tert.-butylmagnesium bromide to be formed in a 20.6% yield. The maximum yield of tert.-butylmagnesium chloride obtained in the several experiments was 58%. In large-sized runs the yield is im- proved as is ...