The ozonolysis of ethylene. Microwave spectrum, molecular structure, and dipole moment of ethylene primary ozonide (1, 2, 3-trioxolane)

JZ Gillies, CW Gillies, RD Suenram…

Index: Gillies, J. Z.; Gillies, C. W.; Suenram, R. D.; Lovas, F. J. Journal of the American Chemical Society, 1988 , vol. 110, # 24 p. 7991 - 7999

Full Text: HTML

Citation Number: 56

Abstract

Abstract: The gas-phase structure of ethylene primary ozonide (CH2CH2000) has been determined from millimeter wave spectra of five isotopic species. Partial substitution, r,, parameters for the lowest energy oxygen envelope conformation (C, symmetry) are r (CC)= 1.546 (3) A, r (C0)= 1.417 (10) A, r (O0)= 1.453 (10) A, r (CHcodo)= 1.088 (5) A, r (CHo,)=

Related Articles:

Mechanism of the ozonolysis of ethylene in the liquid phase

[Fong, Gerald D.; Kuczkowski, Robert L. Journal of the American Chemical Society, 1980 , vol. 102, # 14 p. 4763 - 4768]

Infrared spectrum of the primary ozonide of ethylene in solid xenon

[Kohlmiller, Christopher K.; Andrews, Lester Journal of the American Chemical Society, 1981 , vol. 103, # 10 p. 2578 - 2583]

Environmental effects on the formation of the primary and secondary ozonides of ethylene at cryogenic temperatures

[Samuni; Fraenkel; Haas; Fajgar; Pola Journal of the American Chemical Society, 1996 , vol. 118, # 15 p. 3687 - 3693]

The mechanism of ozone-alkene reactions in the gas phase. A mass spectrometric study of the reactions of eight linear and branched-chain alkenes

[Martinez, Richard I.; Herron, John T.; Huie, Robert E. Journal of the American Chemical Society, 1981 , vol. 103, # 13 p. 3807 - 3820]

Formation of secondary ozonides in the gas phase low-temperature ozonation of primary and secondary alkenes

[Fajgar, Radek; Vitek, Josef; Haas, Yehuda; Pola, Josef Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 2 p. 239 - 248]

More Articles...