Environmental effects on the formation of the primary and secondary ozonides of ethylene at cryogenic temperatures
U Samuni, R Fraenkel, Y Haas, R Fajgar…
Index: Samuni; Fraenkel; Haas; Fajgar; Pola Journal of the American Chemical Society, 1996 , vol. 118, # 15 p. 3687 - 3693
Full Text: HTML
Citation Number: 23
Abstract
Ethylene and ozone were co-deposited in a cryogenic matrix of argon at 15-26 K and of CO2 at 12-20 K. In the argon matrix, no perceptible reaction took place at any temperature below the softening onset of the matrix, while formation of ethylene ozonides (both primary and secondary) was observed at temperatures as low as 25 K in the amorphous CO2 matrix. The ozonides were identified by their infrared spectra, whose assignments were confirmed ...
Related Articles:
Mechanism of the ozonolysis of ethylene in the liquid phase
[Fong, Gerald D.; Kuczkowski, Robert L. Journal of the American Chemical Society, 1980 , vol. 102, # 14 p. 4763 - 4768]
Infrared spectrum of the primary ozonide of ethylene in solid xenon
[Kohlmiller, Christopher K.; Andrews, Lester Journal of the American Chemical Society, 1981 , vol. 103, # 10 p. 2578 - 2583]
[Gillies, J. Z.; Gillies, C. W.; Suenram, R. D.; Lovas, F. J. Journal of the American Chemical Society, 1988 , vol. 110, # 24 p. 7991 - 7999]
[Martinez, Richard I.; Herron, John T.; Huie, Robert E. Journal of the American Chemical Society, 1981 , vol. 103, # 13 p. 3807 - 3820]
[Fajgar, Radek; Vitek, Josef; Haas, Yehuda; Pola, Josef Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 2 p. 239 - 248]