Synthetic Study on Ecteinascidin 743 Starting from D-Glucose
A Endo, T Kann, T Fukuyama
Index: Endo, Atsushi; Kann, Toshiyuki; Fukuyama, Tohru Synlett, 1999 , # 7 p. 1103 - 1105
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Citation Number: 19
Abstract
Abstract: During the course of synthetic study on ecteinascidin 743 (1), key intermediate 5 was prepared. Stereocontrolled synthesis of 5 from D-glucose was accomplished using incorporation of two nitrogen atoms and stereoselective addition of a phenol to an imine as key steps. Key words: ecteinascidin 743, D-glucose, bicyclo [3.3. 1] system, imine
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[Endo, Atsushi; Yanagisawa, Arata; Abe, Masanao; Tohma, Shigemitsu; Kan, Toshiyuki; Fukuyama, Tohru Journal of the American Chemical Society, 2002 , vol. 124, # 23 p. 6552 - 6554]