Synlett

Imine Allylations by Allylic Trichlorotins Derived from α, α-Diisopropylhomoallylic Alcohols with Tin (II) Chloride and N-Chlorosuccinimide

Y Masuyama, N Yamamoto, Y Kurusu

Index: Masuyama, Yoshiro; Yamamoto, Naoko; Kurusu, Yasuhiko Synlett, 2002 , # 12 p. 2113 - 2115

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Abstract

Abstract Allylic trichlorotins, prepared in situ from α, α-diisopropylhomoallylic alcohols with tin (II) chloride and N-chlorosuccinimide in dichloromethane at-40 ºC, cause nucleophilic addition to N-tosylimines or N-tosyliminiums to afford the corresponding α-substituted homoallylic amines.

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