Lewis Acid??Catalyzed Oxidative Allylation: A New Approach for the Synthesis of Homoallylic Alcohols and Amines Directly from Alcohols
VP Srivastava, R Patel…
Index: Srivastava, Vishnu P.; Patel, Rajesh; Yadav, Lal Dhar S. Advanced Synthesis and Catalysis, 2011 , vol. 353, # 5 p. 695 - 700
Full Text: HTML
Citation Number: 6
Abstract
Abstract A new approach for the synthesis of homoallylic alcohols and amines directly from alcohols via one-pot sequential oxidation–Barbier reaction and oxidation–condensation– Barbier reactions, respectively, is reported. The protocol involves the one-pot ferric chloride- catalyzed oxidation of alcohols to the corresponding aldehydes with chloramine-T followed by indium-mediated Barbier allylation with allyl bromide to afford homoallylic alcohols in ...
Related Articles:
[Kurono, Nobuhito; Honda, Eiichi; Komatsu, Fumikazu; Orito, Kazuhiko; Tokuda, Masao Tetrahedron, 2004 , vol. 60, # 8 p. 1791 - 1801]
[Kurono, Nobuhito; Honda, Eiichi; Komatsu, Fumikazu; Orito, Kazuhiko; Tokuda, Masao Tetrahedron, 2004 , vol. 60, # 8 p. 1791 - 1801]
Rhodium-catalyzed reductive allylation of conjugated aldehydes with allyl acetate
[Vasylyev, Maksym; Alper, Howard Journal of Organic Chemistry, 2010 , vol. 75, # 8 p. 2710 - 2713]
[Volla, Chandra M. R.; Markovic, Dean; Laclef, Sylvain; Vogel, Pierre Chemistry - A European Journal, 2010 , vol. 16, # 30 p. 8984 - 8988]
[Masuyama, Yoshiro; Suga, Takanori; Watabe, Akiko; Kurusu, Yasuhiko Tetrahedron Letters, 2003 , vol. 44, # 14 p. 2845 - 2847]