Réactions non classiques au cours de l'alkylation de dérivés d'éléments de la colonne IVB par des réactifs de grignard: IV. étude du mécanisme pour des dérivés de …
MB Lacout-Loustalet, JP Dupin, F Metras…
Index: Lacout-Loustalet,M.B. et al. Journal of Organometallic Chemistry, 1971 , vol. 31, p. 337 - 368
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Citation Number: 13
Abstract
Abstract At a temperature> 100 the transformation of triorganosilanes of the type R 3 SiΣ (Σ Cl or OCH 3) into hydrogenosilanes R 3 SiH by tert-butylmagnesium chloride proceeds by two simultaneous processes: the direct reduction by the organomagnesium compound and the indirect reduction by the magnesium hydride coming from the thermic decomposition of the Grignard reagent. These results can be generalised to the reductive action of various ...
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[Tour, James M.; John, Jens A.; Stephens, Eric B. Journal of Organometallic Chemistry, 1992 , vol. 429, # 3 p. 301 - 310]