Control of conformational flexibility in calix [6] arenes: synthesis and characterisation of triply bridged calix [6] arene—10, 15-dihydro-5h-tribenzo [a, d, g] cyclononene …
HM Chawla, R Shrivastava
Index: Chawla, H. Mohindra; Shrivastava, Rahul Journal of Chemical Research, 2008 , # 6 p. 347 - 353
Full Text: HTML
Citation Number: 0
Abstract
A series of triply bridged symmetrical tert-butylcalix [6] arene—10, 15-dihydro-5H-tribenzo [a, d, g] cyclononene conjugates have been synthesised in excellent yields. It has been observed that the synthesised multi-cavity molecular receptors retain the calix [6] arene and derivatised 10, 15-dihydro-5H-tribenzo [a, d, g] cyclononene units in their cone conformations in solution. While the employed alkyl spacers confer flexibility to the ...
Related Articles:
Designing 129Xe NMR biosensors for matrix metalloproteinase detection
[Wei, Qian; Seward, Garry K.; Hill, P. Aru; Patton, Brian; Dimitrov, Ivan E.; Kuzma, Nicholas N.; Dmochowski, Ivan J. Journal of the American Chemical Society, 2006 , vol. 128, # 40 p. 13274 - 13283]
[Canceill, Josette; Lacombe, Liliane; Collet, Andre Journal of the American Chemical Society, 1985 , vol. 107, # 24 p. 6993 - 6996]
Cryptocalix [6] arenes; molecules with a large cavity
[Janssen, Rob G.; Verboom, Willem; Van Duynhoven, John P. M.; Van Velzen, Ewoud J. J.; Reinhoudt, David N. Tetrahedron Letters, 1994 , vol. 35, # 35 p. 6555 - 6558]