Synthesis of pederic acid and related model studies

S Breitfelder, AC Schuemacher, T Roelle…

Index: Breitfelder, Steffen; Schuemacher, Anne C.; Roelle, Thomas; Kikuchi, Makoto; Hoffmann, Reinhard W. Helvetica Chimica Acta, 2004 , vol. 87, # 5 p. 1202 - 1213

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Citation Number: 9

Abstract

Abstract {[2-(Trimethylsilyl) ethoxy] methyl}(SEM)-protected pederic acid 16 was prepared by deriving the stereogenic center at C (7) from mannitol and those at C (2) and C (3)(mycalamide numbering) from trans-2, 3-dimethyloxirane. Routes to pederamides involving a late oxygenation at C (7) were explored.

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