Copper (II) Complexes of N, N??Diisopropylpicolinamide–Solvatochromic and Thermochromic Phase Change of a Monomeric Complex to a Ferromagnetically …

…, MS Hundal, M Corbella, V Gómez…

Index: Lumb, Isha; Hundal, Maninder Singh; Corbella, Montserrat; Gomez, Veronica; Hundal, Geeta European Journal of Inorganic Chemistry, 2013 , # 27 p. 4799 - 4811

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Citation Number: 7

Abstract

Abstract The synthesis and characterization of mononuclear [Cu (L) 2 (Cl) 2](1), dinuclear [{CuCl (L)} 2 (μ-Cl) 2](2), and another mononuclear complex [Cu (L) 2 (ClO 4) 2](3) with a bidentate N, N-diisopropylpicolinamide ligand (abbreviated L) are described. Complexes 1 and 2 were obtained from the same reaction mixture and show thermo-and solvatochromic behavior. Complex 1 shows irreversible thermochromism by changing into 2 upon heating ...