Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide
H Teare, EG Robins, E Årstad, SK Luthra…
Index: Teare, Harriet; Robins, Edward G.; Arstad, Erik; Luthra, Sajinder K.; Gouverneur, Veronique Chemical Communications, 2007 , # 23 p. 2330 - 2332
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Citation Number: 42
Abstract
A novel [18F] NF reagent and two novel radiochemical transformations have been developed:[18F] NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radiosynthesis of the fluorinated A ring of vitamin D3 has also been completed with success.
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