Reaction of iodo (trimethyl) silane with N, N-dimethyl carboxylic acid amides

MG Voronkov, IP Tsyrendorzhieva, AV Lis…

Index: Voronkov; Tsyrendorzhieva; Lis; Rakhlin Russian Journal of Organic Chemistry, 2010 , vol. 46, # 6 p. 791 - 793

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Citation Number: 2

Abstract

Abstract The reactions of iodo (trimethyl) silane with N, N-dimethylformamide and N, N- dimethylacetamide Me 2 NCOR (R= H, Me) at a molar ratio of 1: 2 involved mainly cleavage of the NC (= O) bond with formation of up to 80% of N, N-dimethyltrimethylsilylamine Me 3 SiNMe 2 and the corresponding acyl iodide RCOI. In the reaction with N, N- dimethylformamide, formyl iodide HCOI was detected for the first time by gas ...